CobaltMaghrebV1, Maroc, Analysis, bibRecord, 000041

trans-Diaquabis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole]cobalt(II) bis(tetrafluoridoborate)

Identifieur interne : 000041 ( Maroc/Analysis ); précédent : 000040; suivant : 000042

trans-Diaquabis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole]cobalt(II) bis(tetrafluoridoborate)

Auteurs : Fouad Bentiss [Maroc] ; Frédéric Capet [France] ; Michel Lagrenée [France] ; Mohamed Saadi [Maroc] ; Lahcen El Ammari [Maroc]

Source :

Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2011.

RBID : PMC:3151744

Abstract

The bidentate 1,3,4-thiadiazole ligand substituted by two 2-pyridyl rings (denoted L) has been found to produce the new monomeric title complex, [Co(C₁₂H₈N₄S)₂(H₂O)₂](BF₄)₂. The thiadiazole and pyridyl rings surrounding the Co atom are almost coplanar [dihedral angle = 4.35 (7)°]. The mean plane defined by these heterocyclic moieties makes a dihedral angle of 18.72 (6)° with the non-coordinated pyridyl ring. The Co²⁺ cation, located at a crystallographic center of symmetry, is bonded to two ligands and two water molecules in a trans configuration in an octahedral environment. The tetrafluoridoborate ions can be regarded as free anions in the crystal lattice. Nevertheless, they are involved in an infinite two-dimensional network along the [010] and [101] directions of O—H⋯F hydrogen bonds.

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151744

DOI: 10.1107/S1600536811020125
PubMed: 21836842
PubMed Central: 3151744

Affiliations:

France, Maroc

Links to Exploration step

PMC:3151744

Le document en format XML

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-Diaquabis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole]cobalt(II) bis(tetrafluoridoborate)</title>
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-Diaquabis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole]cobalt(II) bis(tetrafluoridoborate)</title>
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<front><div type="abstract" xml:lang="en"><p>The bidentate 1,3,4-thiadiazole ligand substituted by two 2-pyridyl rings (denoted <italic>L</italic>
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H<sub>8</sub>
N<sub>4</sub>
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(H<sub>2</sub>
O)<sub>2</sub>
](BF<sub>4</sub>
)<sub>2</sub>
. The thiadiazole and pyridyl rings surrounding the Co atom are almost coplanar [dihedral angle = 4.35 (7)°]. The mean plane defined by these heterocyclic moieties makes a dihedral angle of 18.72 (6)° with the non-coordinated pyridyl ring. The Co<sup>2+</sup>
 cation, located at a crystallographic center of symmetry, is bonded to two ligands and two water molecules in a <italic>trans</italic>
 configuration in an octahedral environment. The tetrafluoridoborate ions can be regarded as free anions in the crystal lattice. Nevertheless, they are involved in an infinite two-dimensional network along  the [010] and [101] directions of O—H⋯F hydrogen bonds.</p>
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Serveur d'exploration sur le cobalt au Maghreb

trans-Diaquabis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole]cobalt(II) bis(tetrafluoridoborate)

trans-Diaquabis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole]cobalt(II) bis(tetrafluoridoborate)

Source :

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri

Pour générer des pages wiki

	Serveur d'exploration sur le cobalt au Maghreb
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Serveur d'exploration sur le cobalt au Maghreb

trans-Diaqua­bis­[2,5-bis­(pyridin-2-yl)-1,3,4-thia­diazole]cobalt(II) bis­(tetra­fluoridoborate)

trans-Diaqua­bis­[2,5-bis­(pyridin-2-yl)-1,3,4-thia­diazole]cobalt(II) bis­(tetra­fluoridoborate)

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Abstract

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trans-Diaquabis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole]cobalt(II) bis(tetrafluoridoborate)

trans-Diaquabis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole]cobalt(II) bis(tetrafluoridoborate)